論文 - 橋本　正人

Crystal Structure of Tetracaesiumdihydrogendecavanadate Trihydrate, Cs₄H₂V₁₀O₂₈·3H₂O. A Layered Crystal Structure of Decavanadate

Masato Hashimoto, Makoto Misono, Mitsuhiro Hibino, Junko Oi, Tetsuichi Kudo

Polyhedron ( PERGAMON-ELSEVIER SCIENCE LTD )  12 ( 22 ) 2745 - 2747   1993年11月  [査読有り]

　概要を見る

The title compound Cs4H2V10O28.3H2O was obtained from a polyvanadate system containing H2O2. No peroxo group or hydrogen peroxide molecule was found in the structure. The polyanions are ordered parallel to the bc-plane forming a layered structure. The water molecules and the caesium ions make a hydrogen bonding network with decavanadate ions and each other to support the whole crystal structure.

CATALYSIS BY HETEROPOLY COMPOUNDS .22. REACTIONS OF ESTERS AND ESTERIFICATION CATALYZED BY HETEROPOLYACIDS IN A HOMOGENEOUS LIQUID-PHASE EFFECTS OF THE CENTRAL ATOM OF HETEROPOLYANIONS HAVING TUNGSTEN AS THE ADDENDA ATOM

CW HU, M HASHIMOTO, T OKUHARA, M MISONO

JOURNAL OF CATALYSIS ( ACADEMIC PRESS INC JNL-COMP SUBSCRIPTIONS )  143 ( 2 ) 437 - 448   1993年10月  [査読有り]

Second Harmonic Generation in Inorganic-Organic Complexes. 1. Control of Bulk Dipolar Alignment of p-Nitroaniline Crystal upon Complexing with Hydrobromic Acid

Takeshi Gotoh, Noritaka Mizuno, Masakazu Iwamoto, Satoshi Hashimoto, Masahiro Kawasaki, Masato Hashimoto, Makoto Misono

Chemistry of Materials   4 ( 3 ) 502 - 504   1992年02月  [査読有り]

DOI

Twisted Slceleton of 1,9-Diaminononane in <i>catena</i>-[<i>catena</i>-<i>μ</i>-(1,9-Diaminononane)cadmium(II)Tetra-{<i>μ</i>-cyanomickelate(II)]-<i>o</i>-Xylene(2/1)

Masato Hashimoto, Takafumi Kitazawa, Tai Hasegawa, Toschitake Iwamoto

Journal Inclusion Phenom. Mol. Recognit. Chem. ( KLUWER ACADEMIC PUBL )  11 ( 2 ) 153 - 158   1991年09月  [査読有り]

　概要を見る

The Hofmann-danon-type o-xylene clathrate Cd[NH2(CH2)9NH2]Ni(CN)4.0.5(CH3)2C6H4, crystallizes in the triclinic space group P1BAR with a = 15.118(3), b = 14.048(4), c = 7.325(1) angstrom, alpha = 91.50(2), beta = 131.66(3), and gamma = 107.50(2)-degrees, V = 1051(1) angstrom 3 and Z = 2. The structure, refined to R = 0.047 using 2851 reflections, reveals a three-dimensional host framework built of the layers of a two-dimensional catena-[cadmium tetra-mu-cyanonickelate(II)] network and of the ambidentate 1,9-diaminononane (danon) bridging the Cd atoms in adjacent networks. The guest o-xylene molecule is accommodated in the cavity formed in the interlayer space similar to that in the Hofmann-daotn-type. The skeleton of the danon in the Cd-NC9N-Cd linkage takes a (gauche)2(trans)8 conformation twisted at the (gauche)2 part in contrast with the all-trans conformation of 1,8-diaminooctane in the Hofmann-daotn-type clathrate. The twisted (gauche)2 part of the danon skeleton occupies the interlayer space to such an extent that void space available for the guest o-xylene molecule decreases to half that in the Hofmann-daotn-type clathrate Cd[NH2(CH2)8NH2]Ni(CN)4.G.

DOI

Preparation and X-ray crystal structure of [N(CH3)4]4[{H(SO4)W3O7(O2)2}2O]

Masato Hashimoto, Toschitake Iwamoto, Hikaru Ichida, Yukiyoshi Sasaki

Polyhedron   10 ( 6 ) 649 - 651   1991年  [査読有り]

　概要を見る

The title peroxotungstosulphate as the first example of a polytungstosulphate has been prepared and its structure determined. The salt crystallizes under the conditions: [WO42-] = 0.3-1.0 mol dm-3, [WO42-]/[SO42-] = 1-1/4, [WO42-]/[H2O2] = 1/2-1/4 and pH &lt
1. The SO42- tetrahedron shares its three vertices with two WO5(O2)2 decahedra and one WO6 octahedron to form a diperoxotritungstosulphate moiety
the polyanion is made of the two moieties bridged with three gm-oxo groups. © 1991.

DOI

CRYSTAL-STRUCTURES OF (18-CROWN-6)-(2-HYDROXYETHYLAMMONIUM) TETRACYANONICKELATE(II) AND 10-AMINODECYLAMMONIUM TETRACYANONICKELTATE(II)

M HASHIMOTO, T IWAMOTO

JOURNAL OF COORDINATION CHEMISTRY ( GORDON BREACH SCI PUBL LTD )  23 ( 1-4 ) 269 - 276   1991年  [査読有り]

<i>Catena</i>-<i>μ</i>-(1,9-diaminononane)cadmium(II) Array in the Crystal Structure of <i>catena</i>-[Bis-<i>catena</i>-<i>μ</i>-(1,9-diaminononane)-Cadmium(II)cis-Di-<i>μ</i>-cyanodicyanomickelate(II)]-(2,4-xylidine)(1/2)Different from That in the 2,3-Isomer Analog

Masato Hashimoto, Toschitake Iwamoto

Chem. Lett. ( CHEMICAL SOC JAPAN )  ( 9 ) 1531 - 1534   1990年09月  [査読有り]

DOI

NOVEL 3-DIMENSIONAL METAL-COMPLEX HOST STRUCTURES OF CATENA-[PROPYLENEDIAMINECADMIUM(II) TETRA-MU-CYANONICKELATE(II)] AND CATENA-[PROPYLENEDIAMINECADMIUM(II) TETRA-MU-CYANOCADMATE(II)]

KM PARK, M HASHIMOTO, T KITAZAWA, T IWAMOTO

CHEMISTRY LETTERS ( CHEMICAL SOC JAPAN )  ( 9 ) 1701 - 1704   1990年09月  [査読有り]

IR, RAMAN AND C-13 NMR-SPECTRA OF PEROXOTUNGSTOOXALATE

M HASHIMOTO, T IWAMOTO, H ICHIDA, Y SASAKI, T KUDO

INORGANICA CHIMICA ACTA ( ELSEVIER SCIENCE SA LAUSANNE )  166 ( 1 ) 17 - 20   1989年12月  [査読有り]

DOI

CRYSTAL-STRUCTURE OF CATENA-[CATENA-BIS-MU-(1,9-DIAMINONONANE)CADMIUM CIS-DI-MU-CYANO-DICYANONICKELATE(II)]-(2,3-XYLIDINE)(1/2)

M HASHIMOTO, T HASEGAWA, H ICHIDA, T IWAMOTO

CHEMISTRY LETTERS ( CHEMICAL SOC JAPAN )  ( 8 ) 1387 - 1390   1989年08月  [査読有り]

OXALATO COMPLEXES DIRECTLY FORMED BY THE REACTION OF INTERSTITIAL CARBIDES WITH HYDROGEN-PEROXIDE

T KUDO, Y SASAKI, M HASHIMOTO, K MATSUMOTO

INORGANICA CHIMICA ACTA ( ELSEVIER SCIENCE SA LAUSANNE )  145 ( 2 ) 205 - 209   1988年05月  [査読有り]

DOI

FORMATION OF PEROXO OXALATO COMPLEX OF TUNGSTEN(VI) DIRECTLY FROM TUNGSTEN CARBIDE AND HYDROGEN-PEROXIDE - A NEW PATH TO THE TOTAL SYNTHESIS OF THE ORGANIC-COMPOUND

T KUDO, Y SASAKI, M HASHIMOTO, H ICHIDA, K MATSUMOTO

INORGANICA CHIMICA ACTA ( ELSEVIER SCIENCE SA LAUSANNE )  133 ( 2 ) 201 - 203   1987年10月  [査読有り]

CRYSTAL-STRUCTURE OF TETRABUTYLAMMONIUM MU-OXALATOBIS(OXODIPEROXOTUNGSTATE) (2-), [(N-C4H9)4N]2[WO(O2)2(C2O4)WO(O2)2]

M HASHIMOTO, T OZEKI, H ICHIDA, Y SASAKI, K MATSUMOTO, T KUDO

CHEMISTRY LETTERS ( CHEMICAL SOC JAPAN )  ( 9 ) 1873 - 1876   1987年  [査読有り]