Recently, anomalous subdiffusion, aging, and scatter of the diffusion coefficient have been reported in many single-particle-tracking experiments, though the origins of these behaviors are still elusive. Here, as a model to describe such phenomena, we investigate a Langevin equation with diffusivity fluctuating between a fast and a slow state. Namely, the diffusivity follows a dichotomous stochastic process. We assume that the sojourn time distributions of these two states are given by power laws. It is shown that, for a nonequilibrium ensemble, the ensemble-averaged mean-square displacement (MSD) shows transient subdiffusion. In contrast, the time-averaged MSD shows normal diffusion, but an effective diffusion coefficient transiently shows aging behavior. The propagator is non-Gaussian for short time and converges to a Gaussian distribution in a long-time limit; this convergence to Gaussian is extremely slow for some parameter values. For equilibrium ensembles, both ensemble-averaged and time-averaged MSDs show only normal diffusion and thus we cannot detect any traces of the fluctuating diffusivity with these MSDs. Therefore, as an alternative approach to characterizing the fluctuating diffusivity, the relative standard deviation (RSD) of the time-averaged MSD is utilized and it is shown that the RSD exhibits slow relaxation as a signature of the long-time correlation in the fluctuating diffusivity. Furthermore, it is shown that the RSD is related to a non-Gaussian parameter of the propagator. To obtain these theoretical results, we develop a two-state renewal theory as an analytical tool.

The mean-square displacement (MSD) is widely utilized to study the dynamical properties of stochastic processes. The time-averaged MSD (TAMSD) provides some information on the dynamics which cannot be extracted from the ensemble-averaged MSD. In particular, the relative standard deviation (RSD) of the TAMSD can be utilized to study the long-time relaxation behavior. In this work, we consider a class of Langevin equations which are multiplicatively coupled to time-dependent and fluctuating diffusivities. Various interesting dynamics models such as entangled polymers and supercooled liquids can be interpreted as the Langevin equations with time-dependent and fluctuating diffusivities. We derive a general formula for the RSD of the TAMSD for the Langevin equation with the time-dependent and fluctuating diffusivity. We show that the RSD can be expressed in terms of the correlation function of the diffusivity. The RSD exhibits the crossover at the long time region. The crossover time is related to a weighted average relaxation time for the diffusivity. Thus the crossover time gives some information on the relaxation time of fluctuating diffusivity which cannot be extracted from the ensemble-averaged MSD. We discuss the universality and possible applications of the formula via some simple examples.

Models with mixed origins of anomalous subdiffusion have been considered important for understanding transport in biological systems. Here one such mixed model, the quenched-trap model (QTM) on fractal lattices, is investigated. It is shown that both ensemble-and time-averaged mean-square displacements (MSDs) show subdiffusion with different scaling exponents, i.e., this system shows weak ergodicity breaking. Moreover, time-averaged MSD exhibits aging and converges to a random variable following the modified Mittag-Leffler distribution. It is also shown that the QTM on a fractal lattice cannot be reduced to the continuous-time random walks if the spectral dimension of the fractal lattice is less than 2.

Phase diagram based on the mean square displacement (MSD) and the distribution of diffusion coefficients of the time-averaged MSD for the stored-energy-driven L,vy flight (SEDLF) is presented. In the SEDLF, a random walker cannot move while storing energy, and it jumps by the stored energy. The SEDLF shows a whole spectrum of anomalous diffusions including subdiffusion and superdiffusion, depending on the coupling parameter between storing time (trapping time) and stored energy. This stochastic process can be investigated analytically with the aid of renewal theory. Here, we consider two different renewal processes, i.e., ordinary renewal process and equilibrium renewal process, when the mean trapping time does not diverge. We analytically show the phase diagram according to the coupling parameter and the power exponent in the trapping-time distribution. In particular, we find that distributional behavior of time-averaged MSD intrinsically appears in superdiffusive as well as normal diffusive regime even when the mean trapping time does not diverge.

We study a class of random walk, the stored-energy-driven Levy flight (SEDLF), whose jump length is determined by a stored energy during a trapped state. The SEDLF is a continuous-time random walk with jump lengths being coupled with the trapping times. It is analytically shown that the ensemble-averaged mean-square displacements exhibit subdiffusion as well as superdiffusion, depending on the coupling parameter. We find that time-averaged mean-square displacements increase linearly with time and the diffusion coefficients are intrinsically random, a manifestation of distributional ergodicity. The diffusion coefficient shows aging in subdiffusive regime, whereas it increases with the measurement time in superdiffusive regime.

The effects of spatial confinements and smooth cutoffs of the waiting time distribution in continuous-time random walks are studied analytically. We also investigate dependences of ergodic properties on initial ensembles (i.e., distributions of the first waiting time). Here, we consider two ensembles: the equilibrium and a typical nonequilibrium ensemble. For both ensembles, it is shown that the time-averaged mean square displacement (TAMSD) exhibits a crossover from normal to anomalous diffusion due to the spatial confinement and this crossover does not vanish even in the long measurement time limit. Moreover, for the nonequilibrium ensemble, we show that the probability density function of the diffusion constant of TAMSD follows the transient Mittag-Leffler distribution, and that scatter in the TAMSD shows a clear transition from weak ergodicity breaking (an irreproducible regime) to ordinary ergodic behavior (a reproducible regime) as the measurement time increases. This convergence to ordinary ergodicity requires a long measurement time compared to common distributions such as the exponential distribution; in other words, the weak ergodicity breaking persists for a long time. In addition, it is shown that, aside from the TAMSD, a class of observables also exhibits this slow convergence to ergodicity. We also point out that, even though the system with the equilibrium initial ensemble shows no aging, its behavior is quite similar to that for the nonequilibrium ensemble. DOI: 10.1103/PhysRevE.87.032130

In entangled polymer systems, there are several characteristic time scales, such as the entanglement time and the disengagement time. In molecular simulations, the longest relaxation time (the disengagement time) can be determined by the mean square displacement (MSD) of a segment or by the shear relaxation modulus. Here, we propose the relative fluctuation analysis method, which is originally developed for characterizing large fluctuations, to determine the longest relaxation time from the center of mass trajectories of polymer chains (the time-averaged MSDs). Applying the method to simulation data of entangled polymers (by the slip-spring model and the simple reptation model), we provide a clear evidence that the longest relaxation time is estimated as the crossover time in the relative fluctuations. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4752768]

We investigate continuous time random walks with truncated alpha-stable trapping times. We prove distributional ergodicity for a class of observables; namely, the time-averaged observables follow the probability density function called the Mittag-Leffler distribution. This distributional ergodic behavior persists for a long time, and thus the convergence to the ordinary ergodicity is considerably slower than in the case in which the trapping-time distribution is given by common distributions. We also find a crossover from the distributional ergodic behavior to the ordinary ergodic behavior.

Fluctuations in the time-averaged mean-square displacement for random walks on hypercubic lattices with static disorder are investigated. It is analytically shown that the diffusion coefficient becomes a random variable as a manifestation of weak ergodicity breaking. For two-and higher-dimensional systems, the distribution function of the diffusion coefficient is found to be the Mittag-Leffler distribution, which is the same as for the continuous-time random walk, whereas for one-dimensional systems a different distribution (a modified Mittag-Leffler distribution) arises. We also present a comparison of these two distributions in terms of an ergodicity-breaking parameter and show that the modified Mittag-Leffler distribution has a larger deviation from ergodicity. Some remarks on similarities between these results and observations in biological experiments are presented.

Nonlinear dynamics of magnetic field lines generated by simple electric current elements are investigated. In general, the magnetic field lines show behavior similar to that of the Hamiltonian systems; in fact, they can be generally transformed into Hamiltonian systems with 1.5 degrees of freedom, obey the Kolmogorov-Arnold-Moser (KAM) theorem, and generate chaotic trajectories. In the case where unperturbed systems are described by two action (slow) and one angle (fast) variables, however, it is found that the periodic orbits of the unperturbed systems vanish for arbitrarily small symmetry-breaking perturbations (a breakdown of the KAM theorem) and drifting or periodic trajectories appear. The mechanism of this phenomenon is investigated analytically by weak nonlinear stability analysis. It is also shown numerically that scattering processes of the perturbed system exhibit typical features of chaotic dynamical systems.

Statistical properties of the transport coefficient for deterministic subdiffusion are investigated from the viewpoint of infinite ergodic theory. We find that the averaged diffusion coefficient is characterized by the infinite invariant measure of the reduced map. We also show that when the time difference is much smaller than the total observation time, the time-averaged mean square displacement depends linearly on the time difference. Furthermore, the diffusion coefficient becomes a random variable and its limit distribution is characterized by the universal law called the Mittag-Leffler distribution.

In various kinds of cultured cells, it has been reported that the membrane potential exhibits fluctuations with long-term correlations, although the underlying mechanism remains to be elucidated. A cardiac muscle cell culture serves as an excellent experimental system to investigate this phenomenon because timings of excitations can be determined over an extended time period in a noninvasive manner through visualization of contractions, although the properties of beat-timing fluctuations of cardiac muscle cells at the single-cell level remains to be fully clarified. In this article, we report on our investigation of spontaneous contractions of cultured rat cardiac muscle cells at the single-cell level. It was found that single cells exhibit several typical temporal patterns of contractions and spontaneous transitions among them. Detrended fluctuation analysis on the time series of interbeat intervals revealed the presence of 1/f(beta) noise at sufficiently large timescales. Furthermore, multifractality was also found in the time series of interbeat intervals. These experimental trends were successfully explained using a simple mathematical model, incorporating correlated noise into ionic currents. From these findings, it was established that singular fluctuations accompanying 1/f(beta) noise and multifractality are intrinsic properties of single cardiac muscle cells.

We investigate the spectral properties of a one-dimensional piecewise linear intermittent map, which has not only a marginal fixed point but also a singular structure suppressing injections of the orbits into neighborhoods of the marginal fixed point. We explicitly derive generalized eigenvalues and eigenfunctions of the Frobenius-Perron operator of the map for classes of observables and piecewise constant initial densities, and it is found that the Frobenius-Perron operator has two simple real eigenvalues 1 and lambda(d)is an element of(-1,0) and a continuous spectrum on the real line [0,1]. From these spectral properties, we also found that this system exhibits a power law decay of correlations. This analytical result is found to be in a good agreement with numerical simulations. Moreover, the system can be extended to an area-preserving invertible map defined on the unit square. This extended system is similar to the baker transformation, but does not satisfy hyperbolicity. A relation between this area-preserving map and a billiard system is also discussed.

Chaotic orbits of the mushroom billiards display intermittent behaviors. We investigate statistical properties of this system by constructing an infinite partition on the chaotic part of a Poincare surface, which illustrates details of chaotic dynamics. Each piece of the infinite partition has a unique escape time from the half disk region, and from this result it is shown that, for fixed values of the system parameters, the escape time distribution obeys a power law 1/t(esc)(3).

The transport properties of a 1-dimensional piecewise linear dynamical system are investigated through the spectrum of its Frobenius-Perron operator. For a class of initial densities, eigenvalues and eigenfunctions of the Frobenius-Perron operator are obtained explicitly. It is also found that in the long length wave limit, this system exhibits normal diffusion and super diffusion called Levy flight. The diffusion constant and stable index are derived from the eigenvalues.

We investigate transport properties of a Hamiltonian system with two degrees of freedom. We found that, for a range of parameter values, transport is superdiffusive, and we numerically comfirmed that this is caused by stickiness of ballistic mode islands. We also note that a Poincare map of our system has properties similar to those of Levy flight.